1. Yuan, C.; Zhu. L; Lan, Y*.; Zhao. Y*.; Ruthenium(II)-catalzyedC-H Difluoromethylation of Ketoxime: Tunning the Regioselectivity from meta to para Position; Angew.Chem. Int. Ed. 2018, DOI: 10.1002/anie.201711221 2. Yuan C., Zhu L., Yang Y., Lan, Y., Zhao. Y.,* Ruthenium(II)-enabledpara-Selective C-H Difluoromethylation of Anilides, Indolines andTetrahydroquinolines; Nat. Commun. 2018, Accepted 3. Zhu, Y.; Chen, X.; Yuan, C.; Li, G.; Zhang, J.; Zhao, Y*., Pd-catalysed ligand-enabledcarboxylate-directed highly regioselective arylation of aliphatic acids. Nat. commun. 2017, 8, 14904. 4. Wang, C.; Chen, C.; Zhang, J.; Han, J.; Wang, Q.; Guo,K.; Liu, P.; Guan, M.; Yao, Y*.; Zhao,Y.*, Easily Accessible Auxiliary for Palladium-Catalyzed IntramolecularAmination of C(sp2)?H and C(sp3)?H Bonds at δ- and ε-Positions. Angew. Chem. Int. Ed. 2014, 53 (37), 9884-9888. 5. Li, G.; Li, D.; Zhang, J.; Shi, D.-Q.*; Zhao, Y.*, Ligand-Enabled Regioselectivity inthe Oxidative Cross-coupling of Arenes with Toluenes and Cycloalkanes UsingRuthenium Catalysts: Tuning the Site-Selectivity from the ortho to metaPositions. ACS Catal. 2017, 7 (6), 4138-4143. 6. Wang, C.; Zhang, L.; Chen, C.; Han, J.; Yao, Y*.; Zhao, Y. *, Oxalyl amide assisted palladium-catalyzed synthesis ofpyrrolidones via carbonylation of [gamma]-C(sp3)-H bonds of aliphatic aminesubstrates. Chem. Sci. 2015, 6 (8), 4610-4614. 7. Wang, Q.; Han, J.; Wang, C.; Zhang, J.; Huang, Z.; Shi,D.*; Zhao, Y.*, Highly site-selective sequential alkenylation of oxalylamide protected phenylpropylamine derivatives via a seven-memberedpalladacycle. Chem. Sci. 2014, 5 (12), 4962-4967. 9. Yuan, C.; Tu, G.; Zhao,Y.*, Rhodium(III)-Catalyzed Selective Monoarylation of beta or gammaC(sp3)-H Bonds Assisted by a Trimethylpyrazole Group. Org. Lett. 2017, 19 (2), 356-359. 10. Chen, C.; Guan, M.; Zhang, J.; Wen, Z. *; Zhao, Y.*, Palladium-Catalyzed Oxalyl Amide Directed Silylation andGermanylation of Amine Derivatives. Org. Lett. 2015, 17 (15), 3646-3649. 11. Guo, K.; Chen, X.; Guan, M.; Zhao, Y.*, Direct ortho-C–H Functionalization of Aromatic AlcoholsMasked by Acetone Oxime Ether via exo-Palladacycle. Org. Lett. 2015, 17(7), 1802-1805. 12. Han, J.; Liu, P.; Wang, C.; Wang, Q.; Zhang, J.; Zhao,Y.; Shi, D.; Huang, Z. *; Zhao, Y.*, Oxalyl Amide AssistedPalladium-Catalyzed Arylation of C(sp2)–H Bond at the δ Position. Org.Lett. 2014, 16 (21),5682-5685. 13. Hu, J.; Li, G.; Yuan, C.; Huang, Z.-B.; Shi, D.-Q.*; Zhao,Y.*, Rhodium(III)-CatalyzedOxidative C–H/C–H Cross-Coupling of Heteroarenes and Masked Benzylamines. Org.Lett. 2016, 18 (23),5998-6001. 14. Chen, X.; Han, J.; Zhu, Y.; Yuan, C.; Zhang, J.*; Zhao,Y.*, Transformation of masked benzyl alcohols to o-aminobenzaldehydesthrough C-H activation: a facile approach to quinazolines. Chem. Commun. 2016, 52 (67), 10241-10244. 15. Guan, M.; Chen, C.; Zhang, J.; Zeng, R.*; Zhao,Y.*, Palladium-catalyzed oxalyl amide assisted direct ortho-alkynylation ofarylalkylamine derivatives at positions. Chem. Commun. 2015, 51 (60), 12103-12106. 16. Guan, M.; Pang, Y.; Zhang, J.;* Zhao, Y*., Pd-Catalyzedsequential [small beta]-C(sp3)-H arylation and intramolecular amination of bondsfor synthesis of quinolinones via an N,O-bidentate directing group. Chem.Commun. 2016, 52 (43), 7043-7046. 17. Han, J.; Zhang, L.; Zhu, Y.; Zheng, Y.; Chen, X.; Huang,Z.-B.; Shi, D.-Q*.; Zhao, Y*., Highly regioselective metaarylation of oxalyl amide-protected [small beta]-arylethylamine via theCatellani reaction. Chem. Commun. 2016, 52 (42), 6903-6906. 18. Chen, C.; Wang, C.; Zhang, J.; Zhao, Y.*, Palladium-Catalyzed ortho-Selective C–H Fluorination ofOxalyl Amide-Protected Benzylamines. J. Org. Chem. 2015, 80 (2), 942-949. 19. Han, J., Y. Zhao,* D. Shi*, Ruthenium-Catalyzed Carbonylation of Oxalyl Amide-Protected Benzylamineswith Isocyanate as the Carbonyl Source. J. Org. Chem. 2017. 10.1021/acs.joc.7b00975 20. Han, J.; Zheng, Y.; Wang, C.; Zhu, Y.; Huang, Z.-B.; Shi,D.-Q.; Zeng, R.*; Zhao, Y.*, Pd-Catalyzed Coupling ofγ-C(sp3)–H Bonds of Oxalyl Amide-Protected Amino Acids with Heteroaryl and ArylIodides. J. Org. Chem. 2016, 81 (13), 5681-5689. 21. Han, J.; Zheng, Y.; Wang, C.; Zhu, Y.; Shi, D.-Q.; Zeng,R.*; Huang, Z.-B. *; Zhao, Y. *, Palladium-Catalyzed Oxalyl Amide-Directed γ-Arylationof Aliphatic Amines. J. Org. Chem. 2015, 80 (18),9297-9306. 22. Hu, J.; Guan, M.; Han, J.; Huang, Z.-B.; Shi, D.-Q.*; Zhao,Y*., Palladium-Catalyzed ortho-Olefination of Phenyl Acetic and PhenylPropylacetic Esters via C–H Bond Activation. J. Org. Chem. 2015, 80 (16), 7896-7904. 23. Zhang, L.; Wang, C.; Han, J.; Huang, Z.-B.*; Zhao,Y.*, Palladium-CatalyzedCarbonylation of β-Arylethylamide Directed by Oxalyl Amide in the Presence ofCarbon Monoxide. J. Org. Chem. 2016, 81 (12), 5256-5262. 24. Hu, J.; Li, G.; Huang, Z.-B.; Zhang, J.; Shi, D.-Q.*; Zhao,Y.*, Pd-Catalyzed thiophenedirected regioselective functionalization of arenes: a direct approach tomultiply-substituted benzyl amines. Org. Chem. Front. 2017. DOI: 10.1039/c7qo00236j 25. Li, G.; Liu, P.; Zhang, J.; Shi, D.-Q.*; Zhao,Y.*, Palladium-catalyzed direct ortho-alkynylation of arylalkylacidderivatives at γ and δ positions via an N,O-bidentate directing group. Org.Chem. Front. 2017. DOI:10.1039/c7qo00327g 26. Guo, K.; Chen, X.; Zhang, J.; Zhao, Y.*,Palladium(II)-Catalyzed Acetoxime Directed ortho-Arylation of AromaticAlcohols. Chem. Eur. J. 2015, 21 (48), 17474-17478. 27. Wang, C.; Chen, C.; Han, J.; Zhang, J.; Yao*, Y.; Zhao, Y.*, Insight into O2-Promoted Base-Catalyzed N-Alkylation ofAmines with Alcohols. Eur. J. Org. Chem. 2015, 2015(13), 2972-2977. 28. Zhang, L.; Huang, Z.-B. *; Zhao, Y.*, Ru-Catalyzed selective C-H oxidativeolefination with N-heteroarenes directed by pivaloyl amide. Org. Chem.Front. 2016, 3 (10), 1271-1275. 29. Han, J., Y. Zhao*,D. Shi*, Pd-Catalyzed Regioselectively Sequential Meta-,Ortho-C–HFunctionalization of Arenes: A Predictable Approach to SynthesisPolysubstituted β-Arylethylamines. Org. Bio. Chem. 2017. DOI: 10.1039/C7OB01135K 30. Guan, M.; Wang, C.; Zhang, J.*; Zhao, Y.,* Practical organic solvent-freeCu(OAc)2 catalyzed aldehyde and imine formation from alcohols under airatmosphere. RSC Adv. 2014, 4 (90), 48777-48782. 31. Liu, P.; Han, J.; Chen, C. P.; Shi, D. Q.*; Zhao, Y*., Palladium-catalyzed oxygenation of C(sp2)-H and C(sp3)-H bondsunder the assistance of oxalyl amide. RSC Adv. 2015,5 (36), 28430-28434. 32. Liu, P.; Han, J.; Wang, Q.; Huang, Z.; Shi, D.; Zeng, R*.; Zhao, Y.*, Palladium(ii)-catalyzed Sequential ortho-olefination of[small beta]-arylethamines with assistance of oxalyl amide. RSC Adv. 2015, 5 (74), 60646-60649. 33. Wang, C.; Han, J., Zhao,Y.* Recent Development in N-Auxilixary-Assisted Intramolecular Aminationfor Amine Substrates. Synlett 2015, 26 (08), 997-1002. 34. 郑永祥、韩健、黄志斌、史达清*、 赵应声*., 草酰胺导向下钯催化的C(sp2)-H和C(sp3)-H键的直接酰氧基化反应. 有机化学 2017. 37, 2028-2033 35. 周盼盼 管明玉 张静宇* 徐凡* 赵应声* 钯催化分子内胺化合成苯并噁嗪酮衍生物. 有机化学 2017. 37, 2066-2072. 36. Pang, Y.; Guan, M., Zeng, R. *; Zhao Y. *, A Practical Approach for theSynthesis of Oxindole and Isatin Derivatives by Pd-Catalyzed IntramolecularAmination Org. Chem. Front. 2017. DOI: 10.1039/C7QO00710H 37. Yuan, C.; Chen, X.; Zhang, J. *; Zhao. Y. *; meta-Selective C–Hdifluoromethylation of various arenes with a versatile ruthenium catalyst. Org.Chem. Front. 2017. 4, 1867. 38. Chen, C.; Zeng, R.; Zhang, J*. Zhao. Y. *; Ruthenium-CatalyzedDifluoroalkylation of 8 Aminoquinoline Amides at the C5-Position. Eur. J. Org. Chem. 2017, DOI: 10.1002/ejoc.201701150. 39. Shi, P., Wang, X., Zeng, X. Zhao, Y.*, Zeng, R.*; Palladium/silver reagent-promotedaryl phosphorylation: flexible synthesis ofsubstituted-3-benzylidene-2-(2-(diphenylphosphoryl)-aryl)-isoindolin-1-one. RSC Adv. 2017, 7, 54277-54280. 博士及博士后期间代表性工作 1. Zhao, Y.; Wang, H.;Hou, X.; Hu, Y.; Lei, A.; Zhang, H.; Zhu, L., J. Am. Chem. Soc. 2006, 128, 15048-15049. 2. Zhao,Y.; Jin, L.; Li, P.; Lei, A., J. Am. Chem. Soc. 2008, 130 (29), 9429-9433. 3. Zhao,Y.; Chen, G., Org. Lett. 2011, 13 (18), 4850-4853. 4. Zhao,Y.; Foo, S. W.; Saito, S., IAngew. Chem. Int. Ed. 2011, 50 (13), 3006-3009. 5. Zhao,Y.; He, G.; Nack, W. A.; Chen, G., Org. Lett. 2012, 14 (12), 2948-2951.
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