研究方向:
有机合成，有机化学实验
22. The [3+3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts, Xinfang Xu and Michael P. Doyle*, Acc. Chem.Res., 2014, 47, 1396-1405.
21. Highly Diasteroselective Intermolecular 1,3-Dipolar Cycloaddition Reactions of Carbonyl Ylides with Aldimines to Aford Sterically Disfavored cis-Oxazolidines, Xinfang Xu, Xin Guo, Xingchun Han, Liping Yang and Wenhao Hu*, Org. Chem. Front., 2014, 1, 181-185.
20. Recent Developments in the Synthetic Uses of Silyl-protected Enoldiazoacetates for Heterocyclic Syntheses, Xinfang Xu* and Michael P. Doyle*, Aust. J. Chem.2014, 67, 365-373.
19. Highly Enantioselective Dearomatizing Formal [3+3]-Cycloaddition Reactions of N-Acyliminopyridinium
Ylides with Electrophilic Enolcarbene Intermediates, Xinfang Xu, Peter Y. Zavalij, and Michael P. Doyle*, Angew. Chem. Int. Ed., 2013, 52, 12664-12668.
18.A Donor-acceptor Cyclopropene as a Dipole Source for a Silver(I) Catalyzed Asymmetric Catalytic [3+3]-Cycloaddition with Nitrones,Xinfang Xu, Peter Y. Zavalij, 2013, 49, 10287
17. Simple and Sustainable Iron-Catalyzed Aerobic C-H Functionalization of N,N Dialkylanilines,Maxim O. Ratnikov, Xinfang Xu, and Michael P. Doyle*, J. Am. Chem. Soc., 2013, 135, 9475-9479 (Article).
16. Dirhodium(II)-Catalyzed Formal [3+2+1]-Annulation of Azomethine Imines with Two Molecules of a Diazo Ketone, Xinfang Xu, Xichen Xu, Peter Y. Zavalij, and Michael P. Doyle*,Chem. Commun., 2013, 49, 2762-2764.
15.Vinylogous Reactivity of Enol Diazoacetates with Donor–Acceptor Substituted Hydrazones. Synthesis of Substituted PyrazoleDerivatives,Xinfang Xu, Peter Y. Zavalij, Wenhao Hu, and Michael P. Doyle*, J. Org. Chem., 2013, 78, 1583-1588 (Article).
14.Synthesis of Tetrahydropyridazines by a Metal–Carbene-Directed Enantioselective Vinylogous N-H Insertion/Lewis Acid-Catalyzed Diastereoselective Mannich Addition,Xinfang Xu, Peter Y. Zavalij, and Michael P. Doyle*, Angew. Chem. Int. Ed., 2012, 51, 9829-9833. （Reviewed by Synfacts: 2012, 8,1181）
13.Rhodium(II)- and Copper(II)-Catalyzed Reactions of Enol Diazoacetates with Nitrones: Metal Carbene versus Lewis Acid Directed Pathways, Yu Qian, Xinfang Xu, Xiaochen Wang, Peter Y. Zavalij, ., 2012, 51, 5900-5903（Reviewed by Synfacts: 2012, 8,0861）
12.Efficient Synthesis of Oxazoles by Dirhodium(II)-catalyzed Reactions of Styryl diazoacetate with Oximes, Xinfang Xu, Peter Y. Zavalij, Wenhao Hu, and Michael P. Doyle*,Chem. Commun., 2012,
48, 11522-11524.
11.Unexpected Catalytic Reactions of Silyl-Protected Enol Diazoacetates with NitrileOxides That Form
5-Arylaminofuran-2(3H)-one-4-carboxylates, Xinfang Xu, Dmitry Shabashov, Peter Y. Zavalij, 2012, 14, 800-803
10.Substrate-Dependent Divergent Outcomes from Catalytic Reactions of Silyl-Protected Enol Diazoacetates with Nitrile Oxides: Azabicyclo[3.1.0]hexanes or 5-Arylaminofuran-2(3H)-ones, Xinfang Xu, Dmitry Shabashov, Peter Y. Zavalij, 2012, 77, 5313-5317
9.Divergent Outcomes of Carbene Transfer Reactions from Dirhodiumand Copper-Based Catalysts Separately or in Combination, Xinfang Xu, Peter Y. Zavalij, ., 2011, 50, 11152-11155（Reviewed by Synfacts: 2011, 9,0976）
8.Highly Enantioselective Catalytic Synthesis ofFunctionalized Chiral Diazoacetoacetates, Xinfang Xu., 2011, 50, 6392-6395
7.Asymmetric Formal [3 + 3]-Cycloaddition Reactions of Nitrones with Electrophilic Vinylcarbene Intermediates, Xiaochen Wang, Xinfang Xu, Peter Y. Zavalij., 2011, 133, 16402-16405
6.Cooperative Catalysis in Highly Enantioselective Mannich-type Three-component Reaction of a Diazoacetophenone with an Alcohol and an Imine, Xinfang Xu, 2011, 47, 797-799（Reviewed by Synfacts: 2011, 3,0304）
5.Multifunctionalized 3-Hydroxypyrroles in a Three-Step, One-Pot Cascade Process from Methyl 3-TBSO-2-diazo-3-butenoate and Nitrones, Xinfang Xu, Maxim O. Ratnikov, Peter Y. Zavalij, and Michael P. Doyle2011, 13, 6122-6125
4.A Strategy to Synthesize Taxol Side Chain and (-)-epi Cytoxazone via Chiral Br?nsted Acid-Rh2(OAc)4
Co-catalyzed EnantioselectiveThree-Component Reactions, Yu Qian, Xinfang Xu, Liqin Jiang, Dipak Prajapati, and Wenhao Hu*,J. Org. Chem.,2010, 75, 7483-7486.
3.Highly Diastereoselective Synthesis of Fully Substituted Tetrahydrofurans by a One-Pot Cascade Reaction of Aryldiazoacetates with Allyl Alcohols, Xinfang Xu, Xinchun Han, Liping Yang, and Wenhao Hu*,Chem. Eur. J., 2009, 15, 12604-12607.（Reviewed by Synfacts: 2010, 2, 0186）
2.Cooperative Catalysis with Chiral Br?nsted Acid-Rh2(OAc)4: Highly Enantioselective Three-Component Reactions of Diazo Compounds with Alcohols and Imines,J. Am. Chem. Soc., 2008, 130, 7782-77831.
1.Selectivity Control in Enantioselective Four-component Reactions of Aryl Diazoacetates with Alcohols,
Aldehydes and Amines: an Efficient Approach to Synthesizing Chiral b-Amino-a-hydroxyesters, Xinfang Xu, Jing Zhou, Liping Yang, and Wenhao Hu*, Chem. Commun., 2008, 44, 6564-6566.（Reviewed
by Synfacts: 2009, 2, 0173）
欢迎报考苏大有机化学研究生。
研究方向:
有机合成，有机化学实验
22. The [3+3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts, Xinfang Xu and Michael P. Doyle*, Acc. Chem.Res., 2014, 47, 1396-1405.
21. Highly Diasteroselective Intermolecular 1,3-Dipolar Cycloaddition Reactions of Carbonyl Ylides with Aldimines to Aford Sterically Disfavored cis-Oxazolidines, Xinfang Xu, Xin Guo, Xingchun Han, Liping Yang and Wenhao Hu*, Org. Chem. Front., 2014, 1, 181-185.
20. Recent Developments in the Synthetic Uses of Silyl-protected Enoldiazoacetates for Heterocyclic Syntheses, Xinfang Xu* and Michael P. Doyle*, Aust. J. Chem.2014, 67, 365-373.
19. Highly Enantioselective Dearomatizing Formal [3+3]-Cycloaddition Reactions of N-Acyliminopyridinium
Ylides with Electrophilic Enolcarbene Intermediates, Xinfang Xu, Peter Y. Zavalij, and Michael P. Doyle*, Angew. Chem. Int. Ed., 2013, 52, 12664-12668.
18.A Donor-acceptor Cyclopropene as a Dipole Source for a Silver(I) Catalyzed Asymmetric Catalytic [3+3]-Cycloaddition with Nitrones,Xinfang Xu, Peter Y. Zavalij, 2013, 49, 10287
17. Simple and Sustainable Iron-Catalyzed Aerobic C-H Functionalization of N,N Dialkylanilines,Maxim O. Ratnikov, Xinfang Xu, and Michael P. Doyle*, J. Am. Chem. Soc., 2013, 135, 9475-9479 (Article).
16. Dirhodium(II)-Catalyzed Formal [3+2+1]-Annulation of Azomethine Imines with Two Molecules of a Diazo Ketone, Xinfang Xu, Xichen Xu, Peter Y. Zavalij, and Michael P. Doyle*,Chem. Commun., 2013, 49, 2762-2764.
15.Vinylogous Reactivity of Enol Diazoacetates with Donor–Acceptor Substituted Hydrazones. Synthesis of Substituted PyrazoleDerivatives,Xinfang Xu, Peter Y. Zavalij, Wenhao Hu, and Michael P. Doyle*, J. Org. Chem., 2013, 78, 1583-1588 (Article).
14.Synthesis of Tetrahydropyridazines by a Metal–Carbene-Directed Enantioselective Vinylogous N-H Insertion/Lewis Acid-Catalyzed Diastereoselective Mannich Addition,Xinfang Xu, Peter Y. Zavalij, and Michael P. Doyle*, Angew. Chem. Int. Ed., 2012, 51, 9829-9833. （Reviewed by Synfacts: 2012, 8,1181）
13.Rhodium(II)- and Copper(II)-Catalyzed Reactions of Enol Diazoacetates with Nitrones: Metal Carbene versus Lewis Acid Directed Pathways, Yu Qian, Xinfang Xu, Xiaochen Wang, Peter Y. Zavalij, ., 2012, 51, 5900-5903（Reviewed by Synfacts: 2012, 8,0861）
12.Efficient Synthesis of Oxazoles by Dirhodium(II)-catalyzed Reactions of Styryl diazoacetate with Oximes, Xinfang Xu, Peter Y. Zavalij, Wenhao Hu, and Michael P. Doyle*,Chem. Commun., 2012,
48, 11522-11524.
11.Unexpected Catalytic Reactions of Silyl-Protected Enol Diazoacetates with NitrileOxides That Form
5-Arylaminofuran-2(3H)-one-4-carboxylates, Xinfang Xu, Dmitry Shabashov, Peter Y. Zavalij, 2012, 14, 800-803
10.Substrate-Dependent Divergent Outcomes from Catalytic Reactions of Silyl-Protected Enol Diazoacetates with Nitrile Oxides: Azabicyclo[3.1.0]hexanes or 5-Arylaminofuran-2(3H)-ones, Xinfang Xu, Dmitry Shabashov, Peter Y. Zavalij, 2012, 77, 5313-5317
9.Divergent Outcomes of Carbene Transfer Reactions from Dirhodiumand Copper-Based Catalysts Separately or in Combination, Xinfang Xu, Peter Y. Zavalij, ., 2011, 50, 11152-11155（Reviewed by Synfacts: 2011, 9,0976）
8.Highly Enantioselective Catalytic Synthesis ofFunctionalized Chiral Diazoacetoacetates, Xinfang Xu., 2011, 50, 6392-6395
7.Asymmetric Formal [3 + 3]-Cycloaddition Reactions of Nitrones with Electrophilic Vinylcarbene Intermediates, Xiaochen Wang, Xinfang Xu, Peter Y. Zavalij., 2011, 133, 16402-16405
6.Cooperative Catalysis in Highly Enantioselective Mannich-type Three-component Reaction of a Diazoacetophenone with an Alcohol and an Imine, Xinfang Xu, 2011, 47, 797-799（Reviewed by Synfacts: 2011, 3,0304）
5.Multifunctionalized 3-Hydroxypyrroles in a Three-Step, One-Pot Cascade Process from Methyl 3-TBSO-2-diazo-3-butenoate and Nitrones, Xinfang Xu, Maxim O. Ratnikov, Peter Y. Zavalij, and Michael P. Doyle2011, 13, 6122-6125
4.A Strategy to Synthesize Taxol Side Chain and (-)-epi Cytoxazone via Chiral Br?nsted Acid-Rh2(OAc)4
Co-catalyzed EnantioselectiveThree-Component Reactions, Yu Qian, Xinfang Xu, Liqin Jiang, Dipak Prajapati, and Wenhao Hu*,J. Org. Chem.,2010, 75, 7483-7486.
3.Highly Diastereoselective Synthesis of Fully Substituted Tetrahydrofurans by a One-Pot Cascade Reaction of Aryldiazoacetates with Allyl Alcohols, Xinfang Xu, Xinchun Han, Liping Yang, and Wenhao Hu*,Chem. Eur. J., 2009, 15, 12604-12607.（Reviewed by Synfacts: 2010, 2, 0186）
2.Cooperative Catalysis with Chiral Br?nsted Acid-Rh2(OAc)4: Highly Enantioselective Three-Component Reactions of Diazo Compounds with Alcohols and Imines,J. Am. Chem. Soc., 2008, 130, 7782-77831.
1.Selectivity Control in Enantioselective Four-component Reactions of Aryl Diazoacetates with Alcohols,
Aldehydes and Amines: an Efficient Approach to Synthesizing Chiral b-Amino-a-hydroxyesters, Xinfang Xu, Jing Zhou, Liping Yang, and Wenhao Hu*, Chem. Commun., 2008, 44, 6564-6566.（Reviewed
by Synfacts: 2009, 2, 0173）
欢迎报考苏大有机化学研究生。